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Pertandingan pertama dimainkan pada 18, 19, 25 dan 26 Februari, dan pertandingan kedua dimainkan pada 10, 11, 17 dan 18 Maret 2020.
{{TwoLegStart}}
{{TwoLegResult|{{nowrap|[[Borussia Mönchengladbach]] {{flagicon|GER}}}}|| 1 |{{flagicon|ENG}} [[Manchester City F.C.|Manchester City]]|ENG| [[Babak gugur Liga Champions UEFA 2020–2021#MönBorussia Mönchengladbach v MCIManchester City|TBD0–2]] | [[Babak gugur Liga Champions UEFA 2020–2021#MCIManchester City v MönBorussia Mönchengladbach|TBD{{small|16 Mar}}]] }}
{{TwoLegResult|[[S.S. Lazio|Lazio]] {{flagicon|ITA}}|| 2 |{{flagicon|GER}} [[FC Bayern München|Bayern München]]|GER| [[Babak gugur Liga Champions UEFA 2020–2021#LAZLazio v BAYBayern München|TBD1–4]] | [[Babak gugur Liga Champions UEFA 2020–2021#BAYBayern München v LAZLazio|TBD{{small|17 Mar}}]] }}
{{TwoLegResult|[[Club Atlético de Madrid|Atlético Madrid]] {{flagicon|SPA}}ESP|| 3 |{{flagicon|ENG}} [[Chelsea F.C.|Chelsea]]|ENG| [[Babak gugur Liga Champions UEFA 2020–2021#ATMAtlético Madrid v CHEChelsea|TBD0–1]] | [[Babak gugur Liga Champions UEFA 2020–2021#CHEChelsea v ATMAtlético Madrid|TBD{{small|17 Mar}}]] }}
{{TwoLegResult|[[RB Leipzig]] {{flagicon|GER}}|| 4 |{{flagicon|ENG}} [[Liverpool F.C.|Liverpool]]|ENG| [[Babak gugur Liga Champions UEFA 2020–2021#LEIRB Leipzig v LIVLiverpool|0–2]] | [[Babak gugur Liga Champions UEFA 2020–2021#LIVLiverpool v LEIRB Leipzig|TBD{{small|10 Mar}}]] }}
{{TwoLegResult|[[F.C.FC Porto|Porto]] {{flagicon|POR}}|| 5 |{{flagicon|ITA}} [[Juventus F.C.|Juventus]]|ITA| [[Babak gugur Liga Champions UEFA 2020–2021#PORPorto v JUVJuventus|TBD2–1]] | [[Babak gugur Liga Champions UEFA 2020–2021#JUVJuventus v PORPorto|TBD{{small|9 Mar}}]] }}
{{TwoLegResult|[[FC Barcelona|Barcelona]] {{flagicon|SPA}}ESP|| 6 |{{nowrap|{{flagicon|FRA}} [[Paris Saint-Germain F.C.|Paris Saint-Germain]]}}|FRA| [[Babak gugur Liga Champions UEFA 2020–2021#BARBarcelona v PSGParis Saint-Germain|1–4]] | [[Babak gugur Liga Champions UEFA 2020–2021#PSGParis Saint-Germain v BARBarcelona|TBD{{small|10 Mar}}]] }}
{{TwoLegResult|[[Sevilla FC|Sevilla]] {{flagicon|SPA}}ESP|| 7 |{{flagicon|GER}} [[Borussia Dortmund]]|GER| [[Babak gugur Liga Champions UEFA 2020–2021#SEVSevilla v DORBorussia Dortmund|TBD2–3]] | [[Babak gugur Liga Champions UEFA 2020–2021#DORBorussia Dortmund v SEVSevilla|TBD{{small|9 Mar}}]] }}
{{TwoLegResult|[[Atalanta B.C.|Atalanta]] {{flagicon|ITA}}|| 8 |{{flagicon|SPA}} [[Real Madrid C.F.CF|Real Madrid]]|ESP| [[Babak gugur Liga Champions UEFA 2020–2021#ATAAtalanta v MADReal Madrid|TBD0–1]] | [[Babak gugur Liga Champions UEFA 2020–2021#MADReal Madrid v ATAAtalanta|TBD{{small|16 Mar}}]] }}
{{End}}<section end=16 />
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