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=== Fluorida klorin ===
TheTiga threefluorida fluoridesklorin ofmembentuk chlorinesekelompok form a subset of thesenyawa [[:en:Interhalogen|interhalogen]] compounds yang semuanya [[diamagnetik]].<ref name="Greenwood824" /> Beberapa turunan kation dan anion diketahui, seperti {{chem|ClF|2|-}}, {{chem|ClF|4|-}}, {{chem|ClF|2|+}}, dan Cl<sub>2</sub>F<sup>+</sup>.<ref name="Greenwood835">Greenwood and Earnshaw, pp. 835–42</ref> Beberapa [[:en:Pseudohalogen|pseudohalida]] klorin juga diketahui, seperti [[sianogen klorida]] (ClCN, linear), klorin [[sianat]] (ClNCO), klorin [[tiosianat]] (ClSCN, unlike its oxygen counterpart), anddan klorin [[azida]] (ClN<sub>3</sub>).<ref name="Greenwood824" />
[[:en:Chlorine_monofluoride|ChlorineKlorin monofluoridemonofluorida]] (ClF) is extremelystabil thermallysecara stabletermal, dan dijual komersial dalam botol 500-gram. Merupakan gas tak berwarna yang melebur pada −155.6 °C dan mendidih pada −100.1 °C. It may be produced by the direction of its elements at 225 °C, though it must then be separated and purified from [[:en:Chlorine_trifluoride|chlorineklorin trifluoridetrifluorida]] and itsdan reactantsreaktannya. ItsKarakteristiknya propertiessendiri areberada mostlydi intermediatetengah-tengah betweenantara thoseklorin ofdan chlorine and fluorinefluor. It will react with many metals and nonmetals from room temperature and above, fluorinating them and liberating chlorine. It will also act as a chlorofluorinating agent, adding chlorine and fluorine across a multiple bond or by oxidation: for example, it will attack [[:en:Carbon_monoxide|carbonkarbon monoxidemonoksida]] to form [[:en:Carbonyl_chlorofluoride|carbonylkarbonil chlorofluorideklorofluorida]], COFCl. It will react analogously with [[:en:Hexafluoroacetone|hexafluoroacetoneheksafluoroaseton]], (CF<sub>3</sub>)<sub>2</sub>CO, withdengan akatalis [[:en:Potassium_fluoride|potassiumkalium fluoridefluorida]] catalystuntuk to producemenghasilkan [[:en:Heptafluoroisopropyl_hypochlorite|heptafluoroisopropylheptafluoroisopropil hypochloritehipoklorit]], (CF<sub>3</sub>)<sub>2</sub>CFOCl; with [[:en:Nitrile|nitriles]] RCN to produce RCF<sub>2</sub>NCl<sub>2</sub>; and with the sulfur oxides SO<sub>2</sub> and SO<sub>3</sub> to produce ClOSO<sub>2</sub>F and ClSO<sub>2</sub>F respectively. ItSenyawa willini alsojuga reactbereaksi exothermicallyeksotermis anddengan violentlysenyawa withyang compoundsmemiliki containinggugus –OH anddan –NH groups, such asseperti waterair:<ref name="Greenwood824" />
: H<sub>2</sub>O + 2 ClF → 2 HF + Cl<sub>2</sub>O
[[Klorin trifluorida]] (ClF<sub>3</sub>) berbentuk cairan tak berwarna volatil yang melebur pada −76.3 °C dan mendidih pada 11.8 °C. ItSenyawa mayini bedapat formeddibuat bydengan directlymemfluorinasi fluorinatinglangsung gaseousgas chlorineklorin oratau chlorineklorin monofluoridemonofluorida atpada 200–300 °C. ItSenyawa isini onemerupakan ofsalah thesatu mostsenyawa reactivekimia knownpaling chemical compoundsreaktif, reactingbereaksi withdengan manybanyak substancessubstansi whichtermasuk inyang ordinarybeberapa circumstancesdiantaranya would be considered chemicallydianggap inert, such asseperti [[asbestos]], concretebeton, anddan sandpasir. Senyawa ini meledak apabila berkontak dengan air dan sebagian besar senyawa organik lain. The list of elements it sets on fire is diverse, containing [[hidrogen]], [[kalium]], [[fosfor]], [[Arsen|arsenik]], [[antimon]], [[Belerang|sulfur]], [[selenium]], [[telurium]], [[bromin]], [[Iodin|iodine]], and powdereddan [[molibdenum]], [[Wolfram|tungsten]], [[rodium]], [[iridium]], andserta [[:en:Iron|iron]]besi bubuk. An impermeable fluoride layer is formed by [[natrium]], [[magnesium]], [[aluminium]], [[seng]], [[timah]], and [[perak]], which may be removed by heating. WhenKetika heateddipanaskan, even suchgolongan [[:en:Noble_metal|noblelogam metalsmulia]] asseperti [[:en:Palladium|palladiumpaladium]], [[platina]], anddan [[:en:Gold|goldemas]] arejuga attackedbereaksi andditambah evenjuga thegolongan [[:en:Noble_gas|noblegas gasesmulia]] seperti [[xenon]] anddan [[radon]] dojuga tak dapat notmengelak escapedari fluorinationfluorinasi. [[Nikel]] containers are usually used due to that metal's great resistance to attack by chlorine trifluoride, stemming from the formation of an unreactive nickel fluoride layer. Its reaction with [[hidrazin]] to form hydrogen fluoride, nitrogen, and chlorine gases was used in experimental rocket motors, but has problems largely stemming from its extreme [[:en:Hypergolic_propellant|hypergolicity]] resulting in ignition without any measurable delay. For these reasons, it was used in bomb attacks during the [[:en:Second_World_War|SecondPerang WorldDunia WarKedua]] by the Nazis. TodaySekarang, itsenyawa isini mostlybanyak useddigunakan indalam nuclearpemrosesan fuelbahan processingbakar nuklir, tountuk oxidisemengoksidasi [[uranium]] tomenjadi [[uranium heksafluorida]] foruntuk itspengayaannya enrichingdan andpemisahan to separate it fromdari [[plutonium]]. ItSenyawa canini actdapat asberperan asebagai fluoridedonor ionatau donorakseptor orion acceptorfluor (Lewisasam baseatau orbasa acidLewis), althoughmeskipun ittak doesterdisosiasi notmerata dissociatemenjadi appreciably intoion {{chem|ClF|2|+}} anddan {{chem|ClF|4|-}} ions.<ref name="Greenwood828">Greenwood and Earnshaw, pp. 828–31</ref>
[[:en:Chlorine_pentafluoride|ChlorineKlorin pentafluoridepentafluorida]] (ClF<sub>5</sub>) isdibuat madedalam onskala abesar largedengan scalefluorinasi byklorin directdengan fluorination of chlorine with excessgas [[:en:FluorineFluor|fluorinefluorin]] gaspada atsuhu 350 °C anddan 250 atm,. andUntuk onskala akecil smalldapat scalediperoleh bydengan reactingmereaksikan metallogam chloridesklorida with fluorinedengan gas atklorin pada suhu 100–300 °C. ItSenyawa ini meltsmelebur atpada −103 °C anddan boilsmendidih atpada −13.1 °C. ItMerupakan isfluonator ayang verysangat strong fluorinating agentkuat, although it is still not asmeski effectivetidak asseefektif chlorineklorin trifluoridetrifluorida. OnlyHanya abeberapa fewreaksi specificstoikiometrik stoichiometricyang reactionstelah have been characteriseddikarakterisasi. [[:en:Arsenic_pentafluoride|ArsenicArsenik pentafluoridepentafluorida]] anddan [[:en:Antimony_pentafluoride|antimonyantimoni pentafluoridepentafluorida]] form ionic adducts of the form [ClF<sub>4</sub>]<sup>+</sup>[MF<sub>6</sub>]<sup>−</sup> (M = As, Sb) and water reacts vigorously as follows:<ref name="Greenwood832">Greenwood and Earnshaw, pp. 832–35</ref>
: 2 H<sub>2</sub>O + ClF<sub>5</sub> → 4 HF + FClO<sub>2</sub>
The product, [[:en:Chloryl_fluoride|chlorylkloril fluoridefluorida]], is one of the five known chlorine oxide fluorides. These range from the thermally unstable FClO to the chemically unreactive [[:en:Perchloryl_fluoride|perchlorylperkloril fluoridefluorida]] (FClO<sub>3</sub>), the other three being FClO<sub>2</sub>, F<sub>3</sub>ClO, and F<sub>3</sub>ClO<sub>2</sub>. All five behave similarly to the chlorine fluorides, both structurally and chemically, and may act as Lewis acids or bases by gaining or losing fluoride ions respectively or as very strong oxidising and fluorinating agents.<ref name="Greenwood875">Greenwood and Earnshaw, pp. 875–80</ref>
== Produksi dan keberadaan ==
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