Piridina: Perbedaan antara revisi

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Baris 5:
| ImageName = Pyridine
| IUPACName = Pyridine
| OtherNames = Azabenzene{{br}}Azine{{br}}py
| Section1 = {{Chembox Identifiers
| SMILES = C1=NC=CC=C1
Baris 37:
| OtherCpds = [[Aniline]]{{br}}[[Pyrimidine]]{{br}}[[Piperidine]]}}
}}
'''Piridina''' adalah sebuah [[senyawa organik]] [[Senyawa heterosiklik|heterosiklik]] yang berbentuk [[cincin aromatik sederhana]]. Rumus kimianya adalah C5H5N. Senyawa ini dipakai sebagai bahan pemula di [[agrokimia]] dan [[farmasi]], dan merupakan bahan [[pelarut]] dan ''reagent'' yang penting. Strukturnya mirip dengan [[benzena]], dimanadi mana sebuah gugus CH di dalam cincin aromatis yang terdiri dari enam [[atom]] diganti dengan [[nitrogen]]. Senyawa ini berbentuk cairan tidak berwarna yang berbau aroma khas seperti [[ikan]]. Cincin piridina banyak terdapat diberbagai senyawa-senyawa penting, termasuk [[nikotinamida]].
 
== Sifat fisika ==
[[FileBerkas:Kristallstruktur Pyridin.png|thumb|Struktur kristal piridina]]
 
Piridina adalah cairan tak berwarna yang mendidih pada suhu 115,2&nbsp;°C dan membeku pada suhu −41,6&nbsp;°C. Berat jenisnya, 0,9819 g/cm<sup>3</sup>, sangat dekat dengan [[air]], dan [[indeks refraktif]] 1,5093 pada [[panjang gelombang]] 589&nbsp;nm dan suhu 20&nbsp;°C.<ref name=lide3448>[[#Lide|Lide]], p. 3–448</ref> Penambahan sampai 40&nbsp;mol% air pada piridina perlahan-lahan mengurangi titik bekunya dari −41.6&nbsp;°C ke −65.0&nbsp;°C.<ref name=str/> [[Momen dipol elektrik]] molekular 2.2 [[debye]].<ref name=roempp>{{cite book|work=Thieme Chemistry|title=RÖMPP Online – Version 3.5|publisher=Georg Thieme |place=Stuttgart|year=2009}}</ref><!-- Pyridine is [[diamagnetism|diamagnetic]] and has a [[Magnetic susceptibility|diamagnetic susceptibility]] of −48.7 × 10<sup>−6</sup> cm<sup>3</sup>·mol<sup>−1</sup>.<ref>[[#Lide|Lide]], p. 3–673</ref> The [[standard enthalpy of formation]] is 100.2 kJ·mol<sup>−1</sup> in the liquid phase<ref name=lide528>[[#Lide|Lide]], p. 5-28</ref> and 140.4 kJ·mol<sup>−1</sup> in the gas phase. At 25&nbsp;°C pyridine has a [[viscosity]]<ref>[[#Lide|Lide]], p. 6-211</ref> of 0.88 mPa/s and [[thermal conductivity]] of 0.166 W·m<sup>−1</sup>·K<sup>−1</sup>.<ref>[[#Lide|Lide]], p. 6–221</ref><ref name="GESTIS"/> The [[enthalpy of vaporization]] is 35.09 kJ·mol<sup>−1</sup> at the [[boiling point]] and normal pressure.<ref name="Majer Svoboda">Majer, V. and Svoboda, V. (1985). ''Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation'', Blackwell Scientific Publications, Oxford, ISBN 0-632-01529-2</ref> The [[enthalpy of fusion]] is 8.28 kJ·mol<sup>−1</sup> at the [[melting point]].<ref>{{cite journal|last1=Domalski|first1=Eugene S.|last2=Hearing|first2=Elizabeth D.|title=Heat Capacities and Entropies of Organic Compounds in the Condensed Phase|journal=Journal of Physical and Chemical Reference Data|volume=25|pages=1|year=1996|doi=10.1063/1.555985|bibcode = 1996JPCRD..25....1D }}</ref>
Baris 52:
* 6-membered rings with six nitrogen atoms: [[hexazine]]
 
== Referensi ==
{{Reflist|2}}
 
== Pustaka ==
* {{cite book|author=Joule, J. A. and Mills, K. |ref=Joule|url=http://books.google.com/books?id=cwe-Ebc64bkC&printsec=frontcover |title=Heterocyclic Chemistry|edition=5th|publisher= Blackwell Publishing|place= Chichester|year= 2010|isbn=1-4051-3300-7}}
* {{cite book|editor=Lide, D. R. |ref=Lide|title=Handbook of Chemistry and Physics|edition=90th|publisher= CRC Press|place= Boca Raton|year= 2009|isbn=978-1-4200-9084-0}}
 
== Pranala luar ==
* [http://www.chemsynthesis.com/six-membered-ring/pyridines/page-1.html Synthesis and propierties of pyridines] at chemsynthesis.com
* [http://www.inchem.org/documents/icsc/icsc/eics0323.htm International Chemical Safety Card 0323]
* [http://www.ilo.org/public/english/protection/safework/cis/products/icsc/dtasht/_icsc03/icsc0323.htm International Chemical Safety Card 0323]
* [http://www.cdc.gov/niosh/npg/npgd0541.html NIOSH Pocket Guide to Chemical Hazards]